1073258-25-9Relevant academic research and scientific papers
Pd-catalyzed asymmetric hydrogenation of C=C bond of α,β- unsaturated ketones
Wang, Duo-Sheng,Wang, Da-Wei,Zhou, Yong-Gui
supporting information; experimental part, p. 947 - 950 (2011/06/17)
Homogenous palladium-catalyzed asymmetric hydrogenation of C=C double bond of ,-unsaturated ketones has been -developed by using palladium(II) trifluoroacetate/(S)-7,7-bis-[di(4-methoxyphenyl]phosphino)-1,1-spirobiindane complex [Pd(OCOCF3)2-(S)-An-SDP] as the catalyst under ambient hydrogen pressure and room temperature with up to 89% ee. Georg Thieme Verlag Stuttgart · New York.
Highly chemo- And enantioselective hydrogenation of linear α,β-unsaturated ketones
Lu, Sheng-Mei,Bolm, Carsten
supporting information; experimental part, p. 7513 - 7516 (2009/09/06)
A study was conducted to report the synthesis of sulfoximine-derived P,N-ligands and their applications in indium-catalyzed asymmetric hydrogenation reactions. Investigations were conducted using linear β,β- disubstituted 1,3-diphenyl-2-butenone as model substrate and iridium, having a ketonic phenyl group and two alkyl substituents at the olefinic β-positions. Methyl ketone with β-methyl and β-phenyl substituent was also applied in the investigations.
