1073371-75-1

Basic information

• Product Name: Methyl(z)-oct-2-enoate-3-boronic acidpinacol ester
• Synonyms: METHYL 3-(4 4 5 5-TETRAMETHYL-1 3 2-DIO&;Methyl (Z)-oct-2-enoate-3-boronic acid pinacol ester;methyl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-octenoate
• CAS NO: 1073371-75-1
• Molecular Formula: C15H29BO5
• Molecular Weight: 300.19876
• Mol File: 1073371-75-1.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Methyl(z)-oct-2-enoate-3-boronic acidpinacol ester(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl(z)-oct-2-enoate-3-boronic acidpinacol ester(1073371-75-1)
• EPA Substance Registry System: Methyl(z)-oct-2-enoate-3-boronic acidpinacol ester(1073371-75-1)

Safety Data

• Hazardous Substances Data: 1073371-75-1(Hazardous Substances Data)

Upstream product

• 111-12-6 methyl 2-octynoate 
• 73183-34-3 bis(pinacol)diborane 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 

Relevant articles and documents

Synthesis and Applications of Unquaternized C-Bound Boron Enolates

A general and facile method to prepare unquaternized C-bound boron enolates by a ligand-controlled O-to-C isomerization is reported. Using this protocol, C-bound pinacolboron enolates have been isolated in pure form for the first time, and have been fully characterized by NMR spectroscopy and X-ray crystallography. In contrast to the general perception, such C-boron enolates are stable without coordinative saturation at the boron. Moreover, C-boron enolates present reactivities that are distinct from the O-boron enolates, and their applications in C-O and C-C bond formations are demonstrated.