107345-16-4Relevant academic research and scientific papers
Synthesis, structure and magnetic property of an asymmetric chlorido bridged dinuclear copper(II) complex containing a didentate Schiff base
Choubey, Somnath,Roy, Subhasis,Chattopadhayay, Soumi,Bhar, Kishalay,Ribas, Joan,Monfort, Montserrat,Ghosh, Barindra Kumar
, p. 39 - 44 (2015)
A dinuclear complex, [Cu2(μ-Cl)2Cl2(pbba)2] (1) [pbba = N-((pyridin-2-yl)benzylidene)benzylamine], has been isolated from the reaction of a 1:1 M ratio of CuCl2·2H2O and pbba in MeOH soluti
Synthesis, characterization and properties of mono-, di- and polynuclear nickel(II) pseudohalide complexes containing bidentate Schiff bases. X-ray structure of [Ni(Ni,Np)2(NCS)2] [Ni,NP =
Banerjee, Jaya,Ghosh, Rajarshi,Rahaman, Sk Hafijur,Dan, Pradip Kumar,Ghosh, Barindra Kumar
, p. 9 - 17 (2008/09/19)
Three different lypes of nickel(II) pseudohalide compounds, [Ni(N i,Np)2(X)-2] [Ni,N P = N-((pyridin-J2-yl)benzylidene) benzylamine; X = N 3-, 1; X = NCS, 2; X = NCOs
Synthesis, structure and luminescence behaviour of copper(II)cyanato complexes containing bidentate N-donor Schiff bases
Chowdhury, Habibar,Ghosh, Rajarshi,Sarkar, Bhola Nath,Banerjee, Sankar Prasad,Ghosh, Barindra Kumar
, p. 1393 - 1400 (2008/09/17)
Two Schiff bases, N-[(pyridin-2-yl)formylidene]benzylamine (pfba) and N-[(pyridin-2-yl)benzylidene]benzylamine (pbba) have been prepared and used to synthesize four pentacoordinated copper(II)cyanato complexes of type [Cu(L) 2(NCO)]X (1-4) [L = pfba, X = ClO4-, 1; L = pfba, X = PF6-, 2; L = pbba, X = ClO4 -, 3; L = pbba, X = PF6-, 4]. The complexes have been characterized on the basis of microanalytical, spectroscopic, magnetic, electrochemical and other physicochemical properties. Structure of [Cu(Pbba)2(NCO)]ClO4 (3) has been solved by X-ray diffraction measurement. Structural analysis reveals that the copper(II) centre in 3 has a distorted trigonal bipyramidal geometry with a CuN5 chromophore coordinated through four N atoms of two bidentate pbba units and one N atom of terminal cyanate. 3 forms a one-dimensional chain through C-H...O hydrogen bond, π...π and C-H...π interactions. The complexes 1-4 exhibit d-d transition and n-π*/π-π* charge transfer transition. Electrochemical electron transfer study reveals copper(II)-copper(I) reduction in methanolic solutions. High-energy intraligand 1(π- π*) fluorescence at room temperature and intraligand 3(π-π*) phosphorescence in glassy solutions (MeOH at 77 K) and in solid states are seen in all the complexes.
