1073483-53-0

Basic information

• Product Name: (2-azidoallyloxy)benzene
• Synonyms: (2-azidoallyloxy)benzene
• CAS NO: 1073483-53-0
• Molecular Weight: 175.19
• Mol File: 1073483-53-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (2-azidoallyloxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (2-azidoallyloxy)benzene(1073483-53-0)
• EPA Substance Registry System: (2-azidoallyloxy)benzene(1073483-53-0)

Safety Data

• Hazardous Substances Data: 1073483-53-0(Hazardous Substances Data)

Upstream product

• 13610-02-1 1-phenoxy-2-propyne 

Downstream Products

• 94830-63-4 4-phenyloxymethyl-2-aminothiazole 
• 2967-88-6 1-fluoro-3-phenoxypropan-2-one 
• 1073483-70-1 ethyl 2-methyl-5-(phenoxymethyl)-1H-pyrrole-3-carboxylate 

Relevant articles and documents

Cis -Specific cyanofluorination of vinyl azides enabled by electron-donor-acceptor complexes: Synthesis of α-azido-β-fluoronitriles

Here we report a novel electron-donor-acceptor (EDA) complex-enabled three-component cyanofluorination of vinyl azides under metal-free conditions in a cis-specific manner. This reaction protocol is operationally simple without exclusion of either moisture or oxygen, allowing access to a wide range of highly-functionalized α-azido-β-fluoronitriles bearing quaternary carbons that are difficult to obtain by existing methods.

Transformation of Alkynes into α- Or β-Difluorinated Alkyl Azides by an Efficient One-Pot Two-Step Procedure

Reported herein an unprecedented 1,2-azide migratory hydroazidation and subsequent gem-difluorination of alkynes accessing β-difluorinated alkyl azides. Importantly, functional group controlled 1,2-azide or 1,2-aryl migration was observed in the case of a

Photoredox-catalysed redox-neutral trifluoromethylation of vinyl azides for the synthesis of α-trifluoromethylated ketones

A redox-neutral, mild, and simple protocol is developed for the synthesis of α-trifluoromethylated ketones from vinyl azides under transition-metal-free conditions. In the presence of organic photoredox catalyst N-methyl-9-mesityl acridinium and sodium trifluoromethanesulfinate, a broad range of substituted vinyl azides were found to react smoothly upon visible-light irradiation, readily furnishing the corresponding products in satisfied yields.