107369-56-2Relevant academic research and scientific papers
Synthesis of Cyclic 3-Aryl-Substituted 1,2-Dicarbonyl Compounds via Suzuki Cross-Coupling Reactions
Lopu?anskaja, Eleana,Paju, Anne,J?rving, Ivar,Lopp, Margus
, p. 1883 - 1890 (2018)
A method for the synthesis of cyclic 3-aryl and heteroaryl-substituted 1,2-dicarbonyl compounds with different ring sizes by using a Suzuki cross-coupling reaction between 3-halo-1,2-dicarbonyl compounds and arylboronic acids is developed. The 3-halo-1,2-dicarbonyl substrates are easily available from 1,2-dicarbonyl compounds. The method is versatile, affording good to high yields of the target compounds.
SYNTHESE D'ARYL-3 CYCLOHEXANEDIONES PAR PHOTOLYSE DES ARENESULFONYLOXY-2 CYCLOHEXENE-2 ONES
Poquet, Anne-Lise,Feigenbaum, Alexandre,Pete, Jean-Pierre
, p. 2975 - 2978 (2007/10/02)
Photolysis of 2-arenesulfonyloxy 2-cyclohexenones 1 is shown to be an efficient way of arylation of 1,2-cyclohexanediones.The reaction, compatible with numerous functional groups on the aromatic ring, allows also heteroarylation.
