107465-54-3

Upstream product

• 107465-50-9 5,5-Dimethyl-2-((Z)-(S)-1-methyl-6-phenyl-hex-2-enyl)-[1,3]dioxane 
• 107465-57-6 (2S,3R,4R)-4-Chloro-2-(5,5-dimethyl-[1,3]dioxan-2-yl)-7-phenyl-heptan-3-ol 

Downstream Products

• 115182-62-2 (2S,3S,4R)-2-(5,5-Dimethyl-[1,3]dioxan-2-yl)-4-methyl-7-phenyl-heptan-3-ol 

Relevant academic research and scientific papers

1,2-ASYMMETRIC INDUCTION ON CONJUGATE ADDITION TO CHIRAL γ-SUBSTITUTED-α,β-UNSATURATED ALDEHYDE

The conjugate addition of organo-cuprate and -copper reagents to chiral γ-substituted-α,β-unsaturated aldehydes yields the anti-adducts predominantly.

Syn-epoxidation of Chiral (Z)-2-Methyl-3-alkenal Acetal via Stereo-selective Bromohydrin Formation

Synthesis of syn-epoxide from chiral (Z)-2-methyl-3-alkenal acetal via stereoselective bromohydrin formation by using a reagent prepared from N-bromosuccinimide (NBS) and dimethyl sulfoxide (DMSO) under irradiation, and regioselective C-C bond formation w

Selective Epoxidation of Chiral 2-Methyl-3,4-unsaturated Aldehyde Acetals

Title compounds were treated with EtAlCl2 or TiCl3OPri and t-butyl hydroperoxide (TBHP) at -78 degC, followed by K2CO3 to give anti-epoxide, which reacted with LiAlH4 at γ-position.