107468-38-2

Upstream product

• 107468-35-9 5-Methoxy-2-phenyl-3H-benzo[e][1,4]diazepine 
• 107468-33-7 5-Methoxy-2-phenyl-1H-benzo[e][1,4]diazepine 
• 39910-68-4 4-azido-2-phenylquinoline 
• 4979-79-7 4-chloro-2-phenylquinoline 

Downstream Products

• 114913-64-3 1-(5-Methoxy-2-phenyl-2,3-dihydro-benzo[e][1,4]diazepin-1-yl)-ethanone 
• 114913-70-1 1-Acetyl-2-phenyl-1,2,3,4-tetrahydro-benzo[e][1,4]diazepin-5-one 
• 107468-41-7 2-Phenyl-1,2,3,4-tetrahydro-benzo[e][1,4]diazepin-5-one 

Relevant academic research and scientific papers

Studies on Diazepines. XXVII. Syntheses of fully Unsaturated 1H- and 3H-1,4-benzodiazepines from 4-Quinolyl Azides

Irradiation of the 4-azidoquinolines (7a-d) in a 1:1 mixture of methanol and dioxane containing sodium methoxide resulted in ring expansion to form the unstable fully unsaturated 1H-1,4-benzodiazepines (9a-d), which were tautomerized to the stable 3H-1,4-