107553-97-9

Upstream product

• 113219-30-0 (E)-5-Benzyloxy-2-methyl-pent-2-enoic acid ethyl ester 
• 95531-99-0 5-(benzyloxy)-2-methylhex-2(E)-en-1-ol 
• 95531-81-0 3-(benzyloxy)-1-bromo-2-methyl-2(E)-hexene 
• 4799-68-2 3-benzyloxypropan-1-ol 
• 95531-81-0 ((E)-6-Bromo-5-methyl-hex-4-enyloxymethyl)-benzene 
• 107554-00-7 2-<(E,E)-10-(benzyloxy)-3,7-dimethyl-5-(phenylthio)-3,7-decadienyl>-1,3-dioxolane 
• 107553-96-8 2-((3E,7E)-10-Benzyloxy-3,7-dimethyl-deca-3,7-dienyl)-[1,3]dioxolane 
• 81027-74-9 2-((E)-3-Methyl-5-phenylsulfanyl-pent-3-enyl)-[1,3]dioxolane 
• 2270-59-9 1-bromo-4-methylpent-3-ene 
• 107554-02-9 diethyl (1-carbethoxy-5-methyl-4-hexenyl)phosphonate 
• 107554-01-8 (E,E)-11-(benzyloxy)-4,8-dimethyl-4,8-undecadien-1-al 

Downstream Products

• 107554-04-1 ((3E,7E,11E)-4,8,16-Trimethyl-12-vinyloxymethyl-heptadeca-3,7,11,15-tetraenyloxymethyl)-benzene 
• 107574-35-6 2-[(5E,9E)-12-Benzyloxy-5,9-dimethyl-2-(5-methyl-1-methylene-hex-4-enyl)-dodeca-5,9-dienyl]-[1,3]dioxolane 
• 107554-05-2 (5E,9E)-12-Benzyloxy-5,9-dimethyl-2-(5-methyl-1-methylene-hex-4-enyl)-dodeca-5,9-dienal 
• 107553-98-0 (2E/Z,6E,10E)-13-(benzyloxy)-6,10-dimethyl-2-(4-methyl-3-pentenyl)-2,6,10-tridecatrien-1-ol 

Relevant academic research and scientific papers

Synthesis of Macrocyclic Terpenoids by Intramolecular Cyclization. 12. Total Synthesis of Methyl Ceriferate I, a 14-Membered Ring Sesterterpene from Scale Insects

Total synthesis of (+/-)-methyl ceriferate I (6), the methyl ester of a cembrane-type sesterterpene isolated from the wax of scale insects, was achieved by means of Wadsworth-Emmons olefination as key step.Three segments, 9, 10, and 11, were connected to

SYNTHESIS OF MACROCYCLIC TERPENOIDS BY INTRAMOLECULAR CYCLIZATION X. TOTAL SYNTHESIS OF METHYL CERIFERATE-I

The methyl ester of (+/-)-ceriferic acid-I, a 14-membered ring sesterterpene isolated from the wax of the scale insect Ceroplastes ceriferus, was synthesized by means of an intramolecular Wittig-type reaction.