1075707-91-3Relevant academic research and scientific papers
Addition reactions of sulfenyl and sulfinyl chlorides with 3-phenyl-1-azabicyclo[1.1.0]butane
Mloston, Grzegorz,Woznicka, Marta,Drabowicz, Jozef,Linden, Anthony,Heimgartner, Heinz
experimental part, p. 1419 - 1429 (2009/02/07)
The reactions of 3-phenyl-1-azabicyclo[1.1.0]butane with α-chlorosulfenyl chlorides and sulfinyl chlorides lead to the corresponding sulfenamides and sulfinamides, respectively, which possess an azetidine ring. It is proposed that a two-step mechanism occurs involving an intermediate carbenium ion, which is formed by the addition of the electrophile at the N-atom and cleavage of the N(1)-C(3) bond. The structures of 9b and 10b are established by X-ray crystallography.
