1075724-23-0Relevant articles and documents
CuH-catalyzed enantioselective intramolecular reductive aldol reactions generating three new contiguous asymmetric stereocenters
Lipshutz, Bruce H.,Amorelli, Benjamin,Unger, John B.
supporting information; experimental part, p. 14378 - 14379 (2009/02/08)
Treatment of β,β-disubstituted-α,β-unsaturated ketones bearing a ketone residue with in situ generated, catalytic CuH ligated by a nonracemic ligand leads to three newly created adjacent chiral centers. Excellent des and ees are obtained for several examples studied. Copyright