1075753-87-5Relevant academic research and scientific papers
Platinum complexes with pyrimidine-functionalized N-heterocyclic carbene ligands-Synthesis and solid state structures
Meyer, Dirk,Zeller, Alexander,Strassner, Thomas
, p. 56 - 61 (2012)
The ligands of the two most successful systems described in the literature for the activation and functionalization of methane have been merged and a series of novel pyrimidine functionalized platinum(II)(NHC) complexes with aryl and alkyl substituents [1
Electron-poor hemilabile dicationic palladium NHC complexes-synthesis, structure and catalytic activity
Schroeter, Felix,Císa?ová, Ivana,Soellner, Johannes,Herdtweck, Eberhardt,Strassner, Thomas
, p. 16638 - 16650 (2018/12/05)
We present a new class of dicationic palladium NHC complexes with two carbene ligands bearing different aryl substituents and a hemilabile pyrimidyl group. They can either be synthesized from the imidazolium salts via the silver transmetalation route to a
Photophysical and photochemical trends in tricarbonyl rhenium(I) N-heterocyclic carbene complexes
Vaughan, Jamila G.,Reid, Brodie L.,Wright, Phillip J.,Ramchandani, Sushil,Skelton, Brian W.,Raiteri, Paolo,Muzzioli, Sara,Brown, David H.,Stagni, Stefano,Massi, Massimiliano
, p. 3629 - 3641 (2014/05/06)
A family of tricarbonyl Re(I) complexes of the formulation fac-[Re(CO) 3(NHC)L] has been synthesized and characterized, both spectroscopically and structurally. The NHC ligand represents a bidentate N-heterocyclic carbene species where the cent
NHC ligands with a secondary pyrimidyl donor for electron-rich palladium(0) complexes
Warsink, Stefan,Chang, I-Hsin,Weigand, Jan J.,Hauwert, Peter,Chen, Jwu-Ting,Elsevier, Cornelis J.
, p. 4555 - 4561 (2011/01/11)
Several (N-2-pyrimidyl-NHC)-palladium(0) complexes have been synthesized in very high yields and purities by transmetalation from the related silver(I) complexes with Pd0(tBuDAB)(ma). The coordination behavior of the heteroditopic ligands was analyzed, and the structure of their complexes was confirmed by NMR and X-ray diffraction studies. The complexes are active catalysts for the transfer hydrogenation of alkynes to Z-alkenes, with activity and selectivity depending on the pyrimidine substituents and the NHC nitrogen substituent. Selectivities toward the Z-alkene as high as 97% were observed.
