107585-03-5Relevant articles and documents
Synthesis of azidochloromethane and azidobromomethane
Banert, Klaus,Joo, Young-Hyuk,Rüffer, Tobias,Walfort, Bernhard,Lang, Heinrich
, p. 2880 - 2882 (2010)
By treatment of tris(azidomethyl)amine with dry hydrogen halide, azidochloromethane and azidobromomethane were prepared. The former product, which is more stable than the latter, was isolated as a colorless liquid. The desired azidohalomethanes are intermediates in the nucleophilic substitution of dihalomethanes to generate diazidomethane but could not be detected in this transformation.