107586-99-2

Upstream product

• 2417-95-0 p-tolyllithium 
• 107197-98-8 RhCl[(CH₃)3CP(CH₂CH₂CH₂P(C₆H₅)2)2] 
• 107586-96-9 Rh(CH₃(C₆H₄))[(CH₃)3CP(CH₂CH₂CH₂P(C₆H₅)2)2] 

Downstream Products

• 107587-03-1 Rh[C₅⁽²⁾H₅N][CH₃(C₆H₄)][(CH₃)3CP(CH₂CH₂CH₂P(C₆H₅)2)2] 
• 107587-02-0 Rh[OC(O)O][CH₃(C₆H₄)][(CH₃)3CP(CH₂CH₂CH₂P(C₆H₅)2)2] 

Relevant academic research and scientific papers

METALLORGANISCHE VERBINDUNGEN DES IRIDIUMS UND RHODIUMS. XXIX. CO2-TRANSFORMATIONEN AM TRIPHOSPHANRHODIUM(I)-KOMPLEX Rh(4-MeC6H4)

The arylrhodium(I) complex Rh(Ar)L (Ar=4-MeC6H4, L=t-BuP(CH2CH2Ch2PPh2)2; I), prepared from RhClL and tolyllithium, reacted with carbon dioxide to give RhL (II) and Rh(O)>(Ar)L (IV).In the presence of ethanol, the ethylcarbonate RhL (III) was obtained.Reaction of I with CO2/O2 yielded the peroxocarbonato derivative Rh(Ar)L (V) which was characterized by X-ray diffraction. 13C and 31P NMR spectroscopy showed the C2O4 compound IV, dissolved in pyridine, to disintegrate to Rh(Ar)L(IVa) and Rh(Ar)(Py)L (IVb).The CO4 derivative V was found to interact with the same solvent to produce the carbonate IVa and pyridine-N-oxide.