107599-30-4Relevant academic research and scientific papers
H-bond mediated self-assembly 1-dimensional array of 3,6-Bis(3′- Pyridyl)-1,2,4,5-tetrazine with trimesic acid
Wang, Wen-Jwu,Wang, Jau-Shuenn
, p. 147 - 152 (2005)
3,6-Bis(3'-pyridyl)-l,2,4,5-tetrazine was prepared by reaction of 3-cyanopyridine with hydrazine. Slow evaporation of 3,6-bis(3′-pyridyl)-l, 2,4,5-tetrazine with trimesic acid, in a 2:1 molar ratio in methanol afforded single crystals of 1 C33H22N12O6, suitable for X-ray analysis. The product was characterized by spectroscopic and single-crystal X-ray diffraction studies. The hydrogen bond mediated self-assembly of 3,6-bis(3'-pyridyl)-l,2,4,5-tetrazine with trimesic acid molecules generates 1-dimensional multi-compartmental arrays in the solid state as revealed by X-ray crystallographic analysis. The crystal structure of 1 is monoclinic with a = 28.445(3), b = 6.7088(10), c = 33.846(4) A, a = 90°, β= 108.112(7°, γ -90°, Z = 8, and space group C2/c. The directional intermodular hydrogen bonding between 3,6-bis(3′-pyridyl)- 1,2,4,5-tetrazine and trimesic acid molecules uses O-H...N and C-H...O interactions, together with intramolecular C-H...N hydrogen bonding, to build up the one-dimensional network structure.
Novel 3,6-unsymmetrically disubstituted-1,2,4,5-tetrazines: S-induced one-pot synthesis, properties and theoretical study
Li, Chen,Ge, Haixia,Yin, Bing,She, Mengyao,Liu, Ping,Li, Xiangdong,Li, Jianli
, p. 12277 - 12286 (2015)
18 unprecedented tetrazines unsymmetrically substituted at C3 and C6 by an aromatic heterocycle have been successfully prepared by the S-induced reaction of aromatic nitriles with hydrazine hydrate under thermal conditions. The spectral property investiga
ADDITIVE FOR IMPARTING LOW HEAT BUILD-UP TO RUBBER COMPONENT
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Paragraph 0189-0193, (2020/08/05)
Provided is an additive for imparting low heat build-up to a rubber component, wherein the additive includes a tetrazine compound represented by general formula (1): (wherein X1 and X2 are the same or different and represent a hydrogen atom or an alkyl, alkylthio, aralkyl, aryl, arylthio, heterocyclic, or amino group; and each of these groups may have one or more substituents), or a salt thereof.
Modification of 1,2,4,5-tetrazine with cationic rhenium(i) polypyridine units to afford phosphorogenic bioorthogonal probes with enhanced reaction kinetics
Choi, Alex Wing-Tat,Tso, Karson Ka-Shun,Yim, Vicki Man-Wai,Liu, Hua-Wei,Lo, Kenneth Kam-Wing
supporting information, p. 3442 - 3445 (2015/03/18)
New phosphorogenic bioorthogonal probes derived from mononuclear and binuclear rhenium(i) polypyridine complexes containing a 1,2,4,5-tetrazine moiety were designed; these complexes displayed substantial dienophile-induced emission enhancement, and accelerated reaction kinetics and could target a protein conjugate in living cells.
