1076-44-4Relevant articles and documents
Synthesis and characterization of acetonitrile-ligated transition-metal complexes with tetrakis(pentafluorophenyl)borate as counteranions
Hijazi, Ahmed K.,Hmaideen, Akef Al,Syukri, Syukri,Radhakrishnan, Narayanan,Herdtweck, Eberhardt,Voit, Brigitte,Kuehn, Fritz E.
, p. 2892 - 2898 (2008)
Complexes with the general formula [MII(NCCH3) 6][TPFB]2 [M = Cr, Fe, Co, Ni, Cu, Zn, (TPFB)- = tetrakis-(pentafluorophenyl)borate] were synthesized and characterized both in the solid state and in solution. According to the spectroscopic data, [TPFB] can be considered as a truly noncoordinating anion. The NCCH3 ligands are lost if the samples are kept at room temperature for extended periods of time. Thermolysis leads to the loss of the NCCH3 ligands and decomposition of the anion above 100°C with the formation of MF2. It has to be noted that distortion of the geometries of the CuII, ZnII and CrII complexes occurs, as evidenced by infrared spectroscopy. The complexes can be easily prepared and obtained in high yields and are moderately sensitive to air. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
Pyridylamino IVB group binuclear metal complex and preparation and application thereof
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Paragraph 0185; 0192-0194, (2020/11/12)
The invention relates to a pyridylamino IVB group binuclear metal complex and the preparation and the application thereof. The structure of the pyridylamino IVB group binuclear metal complex is shownas a formula I, and the pyridylamino IVB group binuclear
donor-acceptor oligogermanes: Synthesis, structure, and electronic properties
Zaitsev, Kirill V.,Kapranov, Andrey A.,Churakov, Andrei V.,Poleshchuk, Oleg Kh.,Oprunenko, Yuri F.,Tarasevich, Boris N.,Zaitseva, Galina S.,Karlov, Sergey S.
, p. 6500 - 6510 (2013/12/04)
A series of oligogermanes, (Me3Si)3GeGeCl 3, (C6F5)3GeGePh3, (C6F5)3GeGe(p-Tol)3, and (C 6F5)2Ge[Ge(p-Tol)3]2, containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these donor-acceptor oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.