107604-18-2Relevant academic research and scientific papers
CHLORIDE-BRIDGED METHYLPALLADIUM(II) DIMERS. PREPARATION, CARBONYLATION AND BRIDGE-SPLITTING REACTIONS WITH TERTIARY PHOSPHINES
Hayashi, Yoshihito,Isobe, Kiyoshi,Nakamura, Yukio,Okeya, Seichi
, p. 127 - 134 (2007/10/02)
(L=PEt3, PBu3 or PMe2Ph) reacts with AlMe3 in ether, THF or a mixture of these solvents depending on L to give in high yield, which has been characterized by IR and NMR spectroscopy as well as elemental analysis.Treatment of with CO yields , while its reaction with L leads to trans-.The preparative method and the characteristic data of these complexes are discussed in comparison with the earlier work on the analogous aryl and aralkyl complexes.
