1076192-94-3Relevant academic research and scientific papers
Desymmetrization of meso-aziridines with TMSNCS using metal salts of novel chiral imidazoline-phosphoric acid catalysts
Nakamura, Shuichi,Ohara, Mutsuyo,Koyari, Madoka,Hayashi, Masashi,Hyodo, Kengo,Nabisaheb, Nadaf Rashid,Funahashi, Yasuhiro
supporting information, p. 4452 - 4455 (2015/01/08)
Highly enantioselective desymmetrization of aziridines with TMSNCS has been developed. Good yield and enantioselectivity were observed by using novel chiral imidazoline-phosphoric acid catalysts. The obtained product can be converted to a chiral β-aminothiol and a β-aminosulfonic acid.
Guanidine-catalyzed enantioselective desymmetrization of meso-aziridines
Zhang, Yan,Kee, Choon Wee,Lee, Richmond,Fu, Xiao,Soh, Julian Ying-Teck,Loh, Esther Mun Foong,Huang, Kuo-Wei,Tan, Choon-Hong
supporting information; experimental part, p. 3897 - 3899 (2011/05/04)
An amino-indanol derived chiral guanidine was developed as an efficient Bronsted base catalyst for the desymmetrization of meso-aziridines with both thiols and carbamodithioic acids as nucleophiles, which provided 1,2-difunctionalized ring-opened products
