1076232-45-5Relevant academic research and scientific papers
N-Cbz sulfilimines as valuable intramolecular nucleophiles for the stereoselective synthesis of (-)-deoxocassine and (+)-desoxoprosophylline
Raghavan, Sadagopan,Mustafa, Shaik
, p. 10055 - 10061 (2008/12/22)
N-Cbz sulfilimine, prepared from the corresponding sulfoxide using the Burgess reagent, has been employed as an intramolecular nucleophile for the regio- and stereoselective preparation of a bromo-carbamate from an alkene. The bromo-carbamate has been utilized as an advanced common synthon for the synthesis of deoxocassine and desoxoprosophylline employing the ene and amidomercuration as key reactions.
