1076239-00-3Relevant academic research and scientific papers
Ambiphilic Reactivity of Vinyl Pd-Oxyallyl for Expeditious Construction of Highly Functionalized Cyclooctanoids
Zuo, Linhong,Ma, Pengchen,Liu, Teng,Chen, Xiangyang,Lavroff, Robert H.,Chen, Wei-Peng,Houk,Guo, Wusheng
supporting information, p. 7330 - 7335 (2021/10/01)
We report the catalytic generation of a vinyl Pd-oxyallyl that dimerizes regiospecifically to form highly functionalized nonbridged cyclooctanoids. Such compounds are otherwise synthetically challenging, but highly useful in synthesis. This vinyl Pd-oxyallyl species demonstrates both electrophilic and nucleophilic properties. DFT calculations elucidate the mechanism and the origins of the chemoselective cyclooctanoid formation.
Pd(0)-catalyzed cross-coupling of allyl halides with α-diazocarbonyl compounds or N-mesylhydrazones: Synthesis of 1,3-diene compounds
Wang, Kang,Chen, Shufeng,Zhang, Hang,Xu, Shuai,Ye, Fei,Zhang, Yan,Wang, Jianbo
, p. 3809 - 3820 (2016/05/09)
With palladium catalysis, allyl bromides or chlorides react with α-diazocarbonyl compounds or N-mesylhydrazones to afford 1,3-diene derivatives. The reaction represents a novel and efficient method for the synthesis of 1,3-butadiene derivatives. Mechanist
Palladium-catalyzed reaction of allyl halides with α-diazocarbonyl compounds
Chen, Shufeng,Wang, Jianbo
supporting information; scheme or table, p. 4198 - 4200 (2009/03/11)
The Pd(OAc)2-catalyzed reaction between α-diazocarbonyl compounds and allyl bromides or chlorides leads to the formation of 1,3-diene derivatives. The Royal Society of Chemistry.
