107624-39-5

Basic information

• Product Name: 2-IODO-4'-METHYLBENZOPHENONE
• Synonyms: 2-IODO-4'-METHYLBENZOPHENONE;UKRORGSYN-BB BBV-5120066
• CAS NO: 107624-39-5
• Molecular Formula: C₁₄H₁₁IO
• Molecular Weight: 322.14
• Mol File: 107624-39-5.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 408°C at 760 mmHg
• Flash Point: 200.6°C
• Appearance: /
• Density: 1.564g/cm³
• Vapor Pressure: 7.24E-07mmHg at 25°C
• Refractive Index: 1.635
• CAS DataBase Reference: 2-IODO-4'-METHYLBENZOPHENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-IODO-4'-METHYLBENZOPHENONE(107624-39-5)
• EPA Substance Registry System: 2-IODO-4'-METHYLBENZOPHENONE(107624-39-5)

Safety Data

• Hazardous Substances Data: 107624-39-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H11IO/c1-10-6-8-11(9-7-10)14(16)12-4-2-3-5-13(12)15/h2-9H,1H3

Upstream product

• 609-67-6 2-Iodobenzoyl chloride 
• 108-88-3 toluene 
• 88-67-5 2-Iodobenzoic acid 
• 36192-63-9 2-amino-4'-methylbenzophenone 
• 118-48-9 isatoic anhydride 
• 133776-41-7 anthranilic acid N-methoxy-N-methylamide 
• 7732-18-5 water 

Downstream Products

• 264278-24-2 1-iodo-2-(4-methylbenzyl)benzene 
• 131003-83-3 4-methyl-1-(4-methylphenyl)isoquinoline 
• 47135-83-1 6-(4′-methylphenyl)phenanthridine 
• 402476-17-9 1-p-toluoyl-2-[(trimethylsilyl)ethynyl]benzene 
• 96375-12-1 1,1'-di-p-tolyl-1H,1'H-[1,1']biisobenzofuranyl-3,3'-dione 

Relevant articles and documents

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Cu(I)-Catalyzed Coupling and Cycloisomerization of Diazo Compounds with Terminal Yne-Alkylidenecyclopropanes: Synthesis of Functionalized Cyclopenta[ b]naphthalene Derivatives

A Cu(I)-catalyzed coupling and cycloisomerization of diazo compounds with terminal yne-alkylidenecyclopropanes (ACPs) has been presented. This reaction starts from the formation of an allenic intermediate in the Cu(I)-catalyzed cross-coupling reaction of a diazo compound with terminal alkyne in yne-tethered ACP and then undergoes a domino cycloisomerization of a 6π-electrocyclization and cyclopropane ring-opening rearrangement to give functionalized cyclopenta[b]naphthalene derivatives in moderate to excellent yields under mild conditions.

Synthesis of cyclic iodonium salts containing an asymmetric carbon atom

We report the synthesis of two iodonium salts with an asymmetric carbon atom in the cation, viz. 3-methyl-10H,10-(4-tolyl)dibenz[b,e]iodinium tetrafluoroborate and the salt of the same cation with the anion of (-)-mono(N-α-phenylethyl)maleic acid amide as well as the synthesis of 3-methyl-10H-dibenz[b,e]-iodinium tetrafluoroborate. 1999 KluwerAcademic/Plenum Publishers.