107657-92-1

Upstream product

• 4551-15-9 phenylthiotrimethylsilane 
• 6705-51-7 3,4-epoxycyclohexene 
• 1165952-91-9 cyclohexa-1,3-diene 
• 108-98-5 thiophenol 

Downstream Products

• 125113-16-8 (rel-1R,2R,3R,6R)-3-hydroxy-2-phenylsulfonyl-7-oxybicyclo<4,1,0>-heptane 
• 125113-16-8 (rel-1S,2R,3R,6S)-3-hydroxy-2-phenylsulfonyl-7-oxybicyclo<4,1,0>-heptane 
• 125113-17-9 cis-1,4-dihydroxy-2-phenylsulfonylcyclohex-2-ene 
• 125113-18-0 cis-4-(t-butyldiphenylsilyloxy)-1-hydroxy-2-phenylsulfonylcyclohex-2-ene 
• 125113-20-4 cis-4-(t-butyldiphenylsilyloxy)-2-dimethylamino-3-phenylsulfonylcyclohex-3-ene 
• 125113-23-7 (rel-1S,2R,3S,4R)-1-(t-butyldiphenylsilyloxy)-2-dimethylamino-3-phenylsulfonyl-4-methylcyclohexane 
• 125113-25-9 (rel-1S,2R,3S,4R)-1-(t-butyldiphenylsilyloxy)-2-dimethylamino-3-phenylsulfonyl-4-phenylcyclohexane 
• 125113-24-8 (rel-1S,2R,3S,4R)-1-(t-butyldiphenylsilyloxy)-2-dimethylamino-3-phenylsulfonyl-4-n-butylcyclohexane 
• 125113-19-1 Methanesulfonic acid (1S,4R)-2-benzenesulfonyl-4-(tert-butyl-diphenyl-silanyloxy)-cyclohex-2-enyl ester 
• 125113-27-1 cis-3-(t-butyldiphenylsilyloxy)-1-phenylsulfonyl-6-butylcyclohex-1-ene 
• 125113-27-1 trans-3-(t-butyldiphenylsilyloxy)-1-phenylsulfonyl-6-butylcyclohex-1-ene 
• 125113-28-2 trans-3-(t-butyldiphenylsilyloxy)-1-phenylsulfonyl-6-phenylcyclohex-1-ene 
• 125113-26-0 cis-3-(t-butyldiphenylsilyloxy)-1-phenylsulfonyl-6-methylcyclohex-1-ene 
• 125113-26-0 trans-3-(t-butyldiphenylsilyloxy)-1-phenylsulfonyl-6-methylcyclohex-1-ene 

Relevant academic research and scientific papers

SN2' ADDITION OF ORGANOMETALLIC REAGENTS TO β-AMINO CYCLOHEXENYL SULFONE DERIVATIVES

Organolithium reagents add to cyclohexenyl sulfone 12 to provide β-amino sulfones that can be eliminated to afford cis-adducts 17a-c.Cuprate reagents undergo trans addition to cyclohexenyl ammonium salt 13 to generate the isomeric vinyl sulfones 18a-c.Thi

SYNTHESIS OF ALLYL SULFIDES VIA A PALLADIUM MEDIATED ALLYLATION

A mild chemo-, regio-, and diastereoselective substitution of allyl carbonates and vinyl epoxides by sulfur nucleophiles catalyzed by palladium can overcome difficulties in and complement conventional displacement without poisoning of the catalyst.