107686-16-8Relevant academic research and scientific papers
Iron-catalyzed ring-opening azidation and allylation of O-heterocycles
Sawama, Yoshinari,Shibata, Kyoshiro,Sawama, Yuka,Takubo, Masato,Monguchi, Yasunari,Krause, Norbert,Sajiki, Hironao
, p. 5282 - 5285 (2013)
We have established the first catalytic C-C and C-N bond formation reactions of O-heterocycles (e.g., tetrahydrofuran, phthalane, and lactone derivatives) using iron trichloride as a catalyst in the presence of TMSN 3 or allylsilanes accompanie
Direct substitution of the hydroxy group in alcohols with silyl nucleophiles catalyzed by indium trichloride
Yasuda, Makoto,Saito, Takahiro,Ueba, Masako,Baba, Akio
, p. 1414 - 1416 (2007/10/03)
Straightforward substitution: An excellent combination of a silyl nucleophile and indium catalyst was used to accomplish the dehydroxylation/ alkylation of alcohols under nearly neutral conditions (see scheme, Si = silyl group) even though this type of reaction usually requires at least an equimolar amount of acid.
Regioselective Ring-Cleavage Reaction of Tetrahydrofurans and Tetrahydropyrans Accompanied by Carbon-Carbon Bond Formation
Oku, Akira,Homoto, Yukio,Harada, Toshiro
, p. 1495 - 1498 (2007/10/02)
Various 2-substituted tetrahydrofurans and tetrahydropyrans were cleaved regioselectively accompanied by a simultaneous carbon-carbon bond formation at the highly substituted α carbon atom by using the reagent system of titanium tetrachloride and allyl- (
