107700-90-3

Upstream product

• 769-40-4 2,3,5,6-tetrafluorothiophenol 
• 563-68-8 thallium(I) acetate 

Downstream Products

• 515843-01-3 [(1,2-bis(diphenylphosphino)ethane)Pt(SC₆F₄H-4)₂] 
• 515843-02-4 cis-[Pd(2,3,5,6-tetrafluorobenzenethiolate)2(1,2-bis(diphenylphosphino)methane)] 
• 184875-96-5 [Mo(CO)3(SC₆F₄H)(C₅H₅)] 
• 184875-97-6 [Mo(CO)2Tl(SC₆F₄H)2(C₅H₅)] 
• 515842-99-6 cis-[Ni(2,3,5,6-tetrafluorobenzenethiolate)2(1,2-bis(diphenylphosphino)ethane)] 
• 184875-95-4 [W(CO)(SC₆F₄H)3(C₅H₅)] 
• 184875-99-8 [WTl(SC₆F₄H)4(C₅H₅)] 
• 515843-00-2 cis-[Pd(2,3,5,6-tetrafluorobenzenethiolate)2(1,2-bis(diphenylphosphino)ethane)] 
• 515843-07-9 [(pentafluorophenyl)2Pt(μ-2,3,5,6-tetrafluorobenzenethiolate)2Ni(1,2-bis(diphenylphosphino)ethane)] 
• 226949-54-8 IrH(SC₆HF₄)2(CO)(P(C₆H₅)3)2 

Relevant academic research and scientific papers

Cis and trans influences on [Pt(SRF)(triphos)]+ complexes (SRF = polyfluorobenzothiolate)

Platinum(II) derivatives of the tridentate ligand Ph2PCH2CH2P(Ph)CH2CH2PPh2 (triphos), including [Pt(SRF)(triphos)](CF3SO3) RF = C6F4CF3-4 1, C6F5 2, C6HF4-4 3, C6H4CF3-4 4, C6H3F2-2,4 5, C6H4F-2 6, C6H4F-4 7 and C6H5 8, have been prepared and characterised. 1H, 19F and 31P solution NMR has been used to evaluate the cis and trans influences of the fluorinated and non-fluorinated benzothiolate ligands, particularly through the cis and trans 1JPt-P values. The crystal and molecular structures of [Pt(SC6F4CF3-4)(triphos)](CF3SO3) 1, with a perfluorinated thiolate ligand, [Pt(SC6HF4-4)(triphos)](CF3SO3) 3, having a fluorinated thiolate, and [Pt(SC6H5)(triphos)](CF3SO3) 8, bearing a non-fluorinated moiety, are discussed as examples of extreme electronegativities.