107728-80-3Relevant academic research and scientific papers
Direct conversion of aromatic 1,3-dioxanes to hydroxypropyl esters with pyridinium hydrobromide perbromide and sodium acetate in water
Sayama, Shinsei
, p. 859 - 864 (2017/06/13)
Various aromatic 1,3-dioxanes were directly converted to respective hydorxypropyl esters with pyridinum hydrobromide perbromide and sodium acetate in water at room temperature.
Improved method for the diimide reduction of multiple bonds on solid-supported substrates
Buszek, Keith R.,Brown, Neil
, p. 3125 - 3128 (2008/02/07)
(Chemical Equation Presented) A mild and improved method for reducing multiple bonds on various resins with diimide is described. The simple procedure readily generates diimide from 2-nitrobenzenesulfonohydrazide and triethylamine at room temperature. A number of representative multiple bonds in various steric and electronic environments were examined, including polar double bonds such as carbonyl and azo, for ease and selectivity of reduction. A general trend of reactivity was identified which revealed, inter alia, that terminal olefins, 1,2-disubstituted olefins, electron-poor olefins, and terminal alkynes were the most easily reduced.
A SIMPLE ELECTROCHEMICAL OXIDATION OF ALDEHYDE ACETALS TO ESTERS IN NEUTRAL SOLUTION
Masui, Masaichiro,Kawaguchi, Tetsuo,Yoshida, Sumiko,Ozaki, Shigeko
, p. 1837 - 1839 (2007/10/02)
Anodic oxidation of aldehyde acetals to esters under very mild conditions is achieved in a neutral solution by utilizing N-hydroxy-phthalimide as a mediator.The oxygen source of the oxidation is thought to be not dioxygen but water.Keywords: acetal; anodic oxidation; mediator; N-hydroxy-phthalimide; ester; glyceride.
