107735-13-7Relevant academic research and scientific papers
Phosphine-Substituted Chelate Ligands, XX. Synthesis and Diastereoselective Complexation of Chiral Phosphinothioformamides, Ph2P(X)C(S)NHHMePh (X = 2e(-), O, S)
Kunze, Udo,Jawad, Hussain,Burghardt, Roland
, p. 1142 - 1150 (2007/10/02)
The ambidentate chiral phosphinothioformamides (-)-S- and (+)-R-Ph2P(X)C(S)NHHMePh with X = 2e(-) (1a), O (1b), S (1c) were obtained from optically pure S- and R-1-phenylethylamine via the isothiocyanate intermediates.Coordination of (-)-1a to CpM(CO)3
