107740-91-0Relevant academic research and scientific papers
ACCES AUX (R)S ACYL-1 VINYL p-TOLYLSULFOXIDES A PARTIR DU (R)S DIMETHYLAMINO-2 p-TOLYLSULFINYL-1 ETHANE. LEURS REACTIVES EN TANT QUE DIENOPHILE.
Maignan, Christian,Guessous, Ahmed,Rouessac, Francis
, p. 2603 - 2606 (2007/10/02)
An efficient sequence is described whose key step involves an Hofmann elimination of (R)S 2-dimethylamino-1 p-tolylsulfinyl ethane to obtain chiral (R)S 1-acyl-vinyl p-tolylsulfoxides.Reactivity and stereoselectivity are discussed in the Diels-Alder reaction.
