107741-13-9Relevant academic research and scientific papers
A novel entry to naturally occurring 5-alkenyl α,β-unsaturated δ-lactones from D-glucose: Syntheses of (+)-acetylphomalactone and (+)-asperlin
Gomez, Ana M.,De Uralde, Beatrix Lopez,Valverde, Serafin,Lopez, J. Cristobal
, p. 1647 - 1648 (1997)
A bicyclic pyranosidic glycoside 6, readily obtained from D-glucose, has been used as the key intermediate in enantioselective syntheses of (+)-acetylphomalactone and (+)-asperlin, in which the configuration at C-5 corresponds to that of the hexopyranosides in the L-sugar series.
Total syntheses of (+)-asperlin, (+)-acetylphomalactone and (5S,6S,7R,8S)-asperlin based on the kinetic resolution of 2-furylmethanols
Yang, Zhi-Cai,Jiang, Xiao-Bin,Wang, Zhi-Min,Zhou, Wei-Shan
, p. 317 - 321 (2007/10/03)
The total syntheses of (+)-asperlin 1, (+)-acetylphomalactone 2 and (5S,6S,7R,8S)-asperlin 3 have been achieved employing the kinetic resolution of unsymmetric divinylmethanol using modified Sharpless reagents, which produced two oxidation products, as a
Total synthesis of (+)-Asperlin
Ramesh,Franck
, p. 137 - 140 (2007/10/02)
A stereochemically unambiguous synthesis of (+)-asperlin from L-rhamnose establishes the configuration of the antibiotic as 4S, 5S, 6S, 7R.
