1078144-09-8Relevant articles and documents
A stereo- and regio-controlled synthesis of bromothiophenyl C-nucleosides. Tandem bromination-ribosylation via halogen dance process
Peyron, Corinne,Navarre, Jean Michel,Dubreuil, Didier,Vierling, Pierre,Benhida, Rachid
, p. 6171 - 6174 (2008)
Metallation-ribosylation of 2-bromothiophene 1 when conducted at room temperature afforded the original glycosylated dibromothiophene 3b following a regiocontrolled halogen transfer-based halogen-dance process. Then, stereocontrolled reduction-cyclization of hemiacetals 3a-c allowed straightforward access to the halogenated thiophenyl-C-nucleosides 6a-c.