107846-82-2Relevant academic research and scientific papers
Synthesis of the Sterically Hindered Bis(pentachlorophenyl)acetic Acid and Derived Stable Free Radicals
O'Neill, Pat,Hegarty, Anthony F.
, p. 4421 - 4426 (2007/10/02)
Bis(pentachlorophenyl)acetic acid esters were synthesized from the α-hydroxydiaryl acetate esters 13 via the free radicals 15 formed on homolytic cleavage of the α-chloro compounds 14.The acid 8 underwent rapid decarboxylation in basic solution (e.g., Et3
STERICALLY STABILIZED α-ACYL FREE RADICALS: α-ISOPROPOXYCARBONYL, N-MORPHOLINOCARBONYL AND CYANO BIS(PENTACHLOROPHENYL)METHYL RADICALS.
Hegarty, A. F.,O'Neill, P.
, p. 901 - 904 (2007/10/02)
The three title radicals, 11a, 11b and 11c have been synthesised by oxidation of the corresponding carbanions with iodine.The radicals are red to purple air stable solids and their ir and esr spectra show considerable interaction between the unpaired elec
