107855-19-6Relevant articles and documents
Dehydrative glycosylation with the Hendrickson reagent
Mossotti, Matteo,Panza, Luigi
experimental part, p. 9122 - 9126 (2011/12/16)
The Hendrickson reagent is able to perform efficiently dehydrative glycosylation of 1-hydroxyglycosyl donors. The reaction occurs under mild conditions through an anomeric oxophosphonium intermediate detected by nuclear magnetic resonance. Further insight into the mechanism was gained by 18O labeling of anomeric OH.
A Rapid and Efficient Synthesis of 1,2-trans-β-Linked Glycosides via Benzyl- or Benzoyl-protected Glycopyranosyl Phosphates
Hashimoto, Shun-ichi,Honda, Takeshi,Ikegami, Shiro
, p. 685 - 687 (2007/10/02)
A highly stereocontrolled construction of 1,2-trans-β-glycosidic linkage with or without neighbouring-group participation has been achieved using benzyl- or benzoyl-protected glycopyranosyl phosphates as glycosyl donors in the presence of trimethylsilyl t