107855-20-9

Basic information

• Product Name: benzyl 2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside
• Synonyms: benzyl 2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside
• CAS NO: 107855-20-9
• Molecular Weight: 1063.3
• Mol File: 107855-20-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: benzyl 2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside(107855-20-9)
• EPA Substance Registry System: benzyl 2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside(107855-20-9)

Safety Data

• Hazardous Substances Data: 107855-20-9(Hazardous Substances Data)

Upstream product

• 27851-29-2 benzyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 130948-38-8 C₅₃H₅₂NO₈PS 
• 35017-04-0 benzyl 2,3,4-tri-O-benzyl-β-D-galactopyranoside 
• 97205-08-8 methyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside 
• 6386-24-9 2,3,4,6-tetra-O-benzyl-D-galactopyranose 
• 165680-88-6 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl diethyl phosphite 

Relevant articles and documents

Dehydrative glycosylation with the Hendrickson reagent

The Hendrickson reagent is able to perform efficiently dehydrative glycosylation of 1-hydroxyglycosyl donors. The reaction occurs under mild conditions through an anomeric oxophosphonium intermediate detected by nuclear magnetic resonance. Further insight into the mechanism was gained by 18O labeling of anomeric OH.

An efficient construction of 1,2-trans-β-glycosidic linkages via benzyl-protected glycopyranosyl P,P-diphenyl-N-(p-toluenesulfonyl)phosphinimidates

-

An efficient approach to O-glycosides through CuBr2 - Bu4NBr mediated activation of glycosides.

-