1078574-75-0Relevant academic research and scientific papers
Tetraaryl-1,3-dioxolane-4,5-dimethanols as catalysts for the addition of trimethylsilyl cyanide to benzaldehyde and the oxirane ring
Belokon',Maleev,Gugkaeva,Moskalenko,Tsaloev,Peregudov,Gagieva,Lyssenko,Khrustalev,Grachev
, p. 1507 - 1514 (2007)
The synthesis of 1,2-, 1,3-, and 1,4-phenylene-bis[(4R,5R)-4,5- di(hydroxydiphenylmethyl)-1,3-dioxolane]s (ortho-, meta-, and para-bis-(R,R)-TADDOLs) and bis[4-{[(4R, 5R)-4,5-di(hydroxydiphenylmethyl)]-1,3- dioxolan-2-yl}phenyl]methane was carried out. The possibilities of the use of these compounds as catalysts for the C-C bond formation in the addition of Me3SiCN to benzaldehyde and the oxirane ring opening in cyclohexene oxide by Me3SiCN were investigated. The catalytic activity of different bis-(R, R)-TADDOLs in this series depends on their structure.
