1079217-13-2Relevant academic research and scientific papers
Coupling reactions of an allenylcarbene complex with alkynes and styrene
Ting, Bin Wen,Wai, Yiu Hung,Sung, Herman H.-Y.,Zhou, Zhongyuan,Williams, Ian D.,Jia, Guochen
, p. 2693 - 2701 (2007)
The allenylcarbene complex [OsCl2{=CPh(η2-CH=C= CHPh)}(PPh3)2] undergoes coupling reactions with HC≡CSiMe3 and PhC≡CC≡CPh to produce the fulvene complexes [OsCl2{η6-C5H2(Ph) (SiMe3)(=CHPh)}(PPh3)] and [OsCl2{η 6-C5H(Ph)2(C≡CPh)(=CHPh)}(PPh 3)], respectively. A similar coupling reaction also occurs between [OsCl2{=CPh(η2-CH=C=CHPh)}(PPh3) 2] and styrene. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
