107977-90-2

Basic information

• Product Name: (E)-(S)-2-Benzyloxy-6-(pyridine-2-sulfinyl)-hex-5-en-3-ol
• CAS NO: 107977-90-2
• Molecular Weight: 331.436
• Mol File: 107977-90-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-(S)-2-Benzyloxy-6-(pyridine-2-sulfinyl)-hex-5-en-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(S)-2-Benzyloxy-6-(pyridine-2-sulfinyl)-hex-5-en-3-ol(107977-90-2)
• EPA Substance Registry System: (E)-(S)-2-Benzyloxy-6-(pyridine-2-sulfinyl)-hex-5-en-3-ol(107977-90-2)

Safety Data

• Hazardous Substances Data: 107977-90-2(Hazardous Substances Data)

Upstream product

• 65063-38-9 pyridin-2-yl allyl sulfide 
• 89818-47-3 (+/-)-2-(allylsulfinyl)pyridine 
• 81445-44-5 (S)-2-(benzyloxy)propanal 

Relevant articles and documents

STEREOSELECTIVE SYNTHESIS OF POLYOLS PRECURSORS BY ALLYL SULPHINYL ANION ADDITION TO CHIRAL ALKOXY ALDEHYDES

Tandem condensation of chiral α-alkoxy and α,β-dialkoxy aldehydes with allylic sulphinyl anion, and thiophile promoted desulphurization of the resulting α-substituted allylic sulphoxide afford (E)-5-alkoxy-(or 5,6-dialkoxy)-2-alkene-1,4-diols, advanced polyols precursors, the major stereochemical path occuring via a Felkin-Ahn (non chelation control) mode.