107978-11-0Relevant articles and documents
Asymmetric Sulfenylation of Tin(II) Enolates of Ketones and 3-Acyl-2-oxazolidones. Application to the Synthesis of Optically Active Epoxides
Yura, Takeshi,Iwasawa, Nobuharu,Clark, Richard,Mukaiyama, Teruaki
, p. 1809 - 1812 (1986)
In the presence of chiral diamines, the reaction between tin(II) enolates of ketones or 3-acyl-2-oxazolidones and thiosulfonates proceeds smoothly to give the corresponding β-keto sulfides with high enetioselectivity.Further, optically active epoxides are prepared from these β-keto sulfides.