108078-65-5Relevant articles and documents
Copper-Catalyzed Oxysulfenylation of Enolates with Sodium Sulfinates: A Strategy to Construct Sulfenylated Cyclic Ethers
Gao, Yinglan,Gao, Yang,Tang, Xiaodong,Peng, Jianwen,Hu, Miao,Wu, Wanqing,Jiang, Huanfeng
supporting information, p. 1158 - 1161 (2016/03/15)
A new copper-catalyzed oxysulfenylation reaction of enolates with sodium sulfinates has been disclosed. A series of sulfenylated heterocycles including four- and seven-membered cyclic ether were obtained in mild to good yields. This reaction is proposed to go through a radical process, and the sulfur radical (RS?) may be a reactive species.
Synthesis of functionalized γ-and δ-lactones via polymer-bound epoxides
Le Hetet, Claire,David, Michelle,Carreaux, Francois,Carboni, Bertrand,Sauleau, Armelle
, p. 5153 - 5156 (2007/10/03)
Solid phase synthesis of epoxides from alkenoic acids followed by ring-opening reactions with sodium azide or thiophenols and subsequent cleavage from the polymeric support afford γ- and δ-lactones in good yields and high purity.
TRIFLUOROACETOXYSULPHENYLATION OF UNSATURATED NITRILES AS A ROUTE TO LACTONES
Samii, Zakaria K M Abd El,Ashmawy, Mohamed I Al,Mellor, John M
, p. 5293 - 5296 (2007/10/02)
Use of manganic acetate as oxidant permits efficient trifluoroacetoxysulphenylation of unsaturated nitriles with organic disulphides.The adducts in a cobaltous chloride promoted hydrolysis afford alkyl- or aryl-thio substituted lactones.
