108161-77-9

Upstream product

• 80900-46-5 methyl 2,6-dimethoxy-1-(3'-trimethylsiloxypentyl)-2,5-cyclohexadiene-1-carboxylate 
• 80900-44-3 (1-Ethyl-3-iodopropoxy)trimethylsilane 
• 108161-72-4 rac-1-iodo-pentan-3-ol 
• 32541-33-6 1-chloro-3-pentanol 
• 1629-58-9 4-penten-3-one 
• 108162-05-6 1-iodo-3-trimethylsiloxypent-3-ene 
• 82939-66-0 methyl 2,6-dimethoxy-2,5-cyclohexadiene-1-carboxylate 
• 108161-75-7 methyl 1-(3'-hydroxypentyl)-2,6-dimethoxy-2,5-cyclohexadiene-1-carboxylate 

Relevant academic research and scientific papers

Practical and versatile syntheses of angular hydroxymethylated decalones

The practical and versatile syntheses of angular hydroxymethylated decalones as potential synthetic intermediates for terpenoids are described. Particularly angular hydroxymethylated bicyclodecanedione 1 has been synthesized in 45 % overall yield from met

IMPROVED METHODS FOR THE REDUCTIVE ALKYLATION OF METHOXYBENZOIC ACIDS AND ESTERS: APPLICATION TO THE SYNTHESIS OF BICYCLIC KETONES

A series of methoxybenzoic acids and esters was reduced by metal-ammonia solutions and the resulting 1,4-dihydro products were either alkylated subsequently.Three different types of alkyl iodies were employed to introduce the elements of a butanone or pentanone side-chain as a prelude to adding a fused six-membered ring, thereby completing the preparation of several analogues of the Wieland-Miescher ketone 4a in which the angular substituent was oxygenated.