108167-50-6Relevant articles and documents
Application of the Sonogashira coupling reaction to the stereoselective synthesis of chiral 1,3-dienol ethers
Dussault, Patrick H.,Sloss, Darby G.,Symonsbergen, David J.
, p. 1387 - 1389 (2007/10/03)
Sonogashira couplings of 2-iodo enol ethers or ynol ethers provide enynes which undergo semihydrogenation to afford 4-alkyl-1,3-dienol ethers. (1Z, 3E), (1E, 3Z) and (1Z, 3Z)-4-alkyl-1,3-dienol ethers are accessible using this strategy.
The photochemistry of acetylenic ethers. A novel carbon-oxygen to carbon-carbon bond conversion
Smith, Bradley A.,Callinan, Andrew J.,Swenton, John S.
, p. 2283 - 2286 (2007/10/02)
Irradiation of acetylenic ethers in methanol gives homologated esters via a formal [1,3]-oxygen-to-carbon migration involving a ketene intermediate.