1081979-44-3Relevant articles and documents
Metal-free oxidative spirocyclization of hydroxymethylacrylamide with 1,3-dicarbonyl compounds: A new route to spirooxindoles
Wang, Hua,Guo, Li-Na,Duan, Xin-Hua
, p. 5254 - 5257 (2013/11/06)
A metal-free oxidative spirocyclization of hydroxymethylacrylamide with 1,3-dicarbonyl compounds is described. The reaction proceeds through tandem dual C-H functionalization and intramolecular dehydration, in which two new C-C bonds and one C-O bond were formed. This method affords a novel and straightforward access to various spirooxindoles under mild conditions.
Photochemical elimination of leaving groups from zwitterionic intermediates generated via electrocyclic ring closure of α,β-unsaturated anilides
Jia, Jinli,Sarker, Majher,Steinmetz, Mark G.,Shukla, Ruchi,Rathore, Rajendra
experimental part, p. 8867 - 8879 (2009/04/04)
(Chemical Equation Presented) Methacrylanilides, ArN(CH3) COC(CH2LG)=CH2, with allylic leaving groups (LG - = BocAla, PhCO2-, PhCH2CO 2-, PhO-) u