108199-45-7

Basic information

• Product Name: 1-n-butyl-1-t-butylazocyclohexane
• CAS NO: 108199-45-7
• Molecular Weight: 224.39
• Mol File: 108199-45-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-n-butyl-1-t-butylazocyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-n-butyl-1-t-butylazocyclohexane(108199-45-7)
• EPA Substance Registry System: 1-n-butyl-1-t-butylazocyclohexane(108199-45-7)

Safety Data

• Hazardous Substances Data: 108199-45-7(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 542-69-8 1-iodo-butane 
• 37426-22-5 cyclohexanone tert-butylhydrazone 

Relevant articles and documents

AZO ANIONS IN SYNTHESIS. PT 1. t-BUTYLHYDRAZONES AS ACYL-ANION EQUIVALENTS

The lithium salts of aldehyde t-butylhydrazones react with electrophiles (aldehydes, ketones, alkyl halides, crotonates) to form C-trapped t-butylazo-compounds; tautomerisation and hydrolysis gave α-hydroxy ketones, ketones, and γ-keto esters in good yield, thereby providing a convenient new acyl-anion equivalent.Reaction of these lithium salts with aldehydes and ketones, followed by elimination provided a new route to azo alkenes.