1082203-06-2Relevant academic research and scientific papers
Regiocontrolled addition of arylboronic acids to allenes using palladium and platinum catalysts
Yoshida, Masahiro,Matsuda, Kennosuke,Shoji, Yasunobu,Gotou, Takahiro,Ihara, Masataka,Shishido, Kozo
scheme or table, p. 5183 - 5186 (2009/06/06)
(Chemical Equation Presented) Studies about the regiocontrolled addition of arylboronic acids to allenes using a palladium or a platinum catalyst have been described. The selectivity of the reaction can be altered by the choice of the metal reagent and base. Contrary to the formation of endo-olefinic products in the reactions using hydroxopalladium complex, predominant production of exo-olefinic products was observed by the reaction with hydroxoplatinum complex.
