108233-82-5

Basic information

• Product Name: Hexanoic acid, 2-(2-propenyl)-, 2-propenyl ester
• CAS NO: 108233-82-5
• Molecular Formula: C12H20O2
• Molecular Weight: 196.29
• Mol File: 108233-82-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Hexanoic acid, 2-(2-propenyl)-, 2-propenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Hexanoic acid, 2-(2-propenyl)-, 2-propenyl ester(108233-82-5)
• EPA Substance Registry System: Hexanoic acid, 2-(2-propenyl)-, 2-propenyl ester(108233-82-5)

Safety Data

• Hazardous Substances Data: 108233-82-5(Hazardous Substances Data)

Upstream product

• 108233-81-4 diallyl butylmalonate 

Relevant articles and documents

Palladium-Catalyzed Decarboxylation-Allylation of Allylic Esters of α-Substituted β-Keto Carboxylic, Malonic, Cyanoacetic, and Nitroacetic Acids

Decarboxylation-allylation of allylic β-keto carboxylates using Pd(OAc)2-PPh3 or Pd2(dba)3*CHCl3-dppe as a catalyst proceeds smoothly to give α-allylated ketones.The reaction is highly regioselective.In some cases, diallylated ketones are obtained with allylic esters bearing an active proton(s).Also rhodium, molybdenum, and nickel complexes sre active catalysts in this reaction.Similarly allylic esters of α-substituted malonates, cyanoacetates, and nitroacetate undergo the palladium-catalyzed decarboxylation-allylation to afford allylated acetate, acetonitrile, and nitromethane, respectively.The mechanisms of these palladium-cataly zed decarboxylation-allylations are discussed