108264-21-7

Basic information

• Product Name: 2-((Z)-3-Methoxy-2-trimethylsilanylmethyl-allyl)-cyclohexanone
• CAS NO: 108264-21-7
• Molecular Weight: 254.445
• Mol File: 108264-21-7.mol

Chemical Properties

• CAS DataBase Reference: 2-((Z)-3-Methoxy-2-trimethylsilanylmethyl-allyl)-cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-((Z)-3-Methoxy-2-trimethylsilanylmethyl-allyl)-cyclohexanone(108264-21-7)
• EPA Substance Registry System: 2-((Z)-3-Methoxy-2-trimethylsilanylmethyl-allyl)-cyclohexanone(108264-21-7)

Safety Data

• Hazardous Substances Data: 108264-21-7(Hazardous Substances Data)

Upstream product

• 56407-82-0 2-<(trimethylsilyl)methyl>propenal 
• 83378-96-5 O-trimethylsilyl-2-(trimethylsilylmethyl)prop-2-en-1-ol 
• 81302-80-9 2-(trimethylsilylmethyl)prop-2-en-1-ol 
• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 108264-16-0 3,3-dimethoxy-2-(trimethylsilylmethyl)prop-1-ene 

Relevant articles and documents

THE PREPARATION AND REACTIONS WITH AN O-SILYLATED ENOLATE OF AN ALLYLSILANE BIFUNCTIONAL ANNULATING REAGENT

The preparation and reactions of allylsilance-acetal (13) with various silyl enol ethers are described.This results in the one-pot synthesis of fused and spiro cyclopentanes by using a 1,3-bifunctional annulating reagent in which the two reactive centres

NOVEL ANNULATION REACTIONS: A SIMPLE PREPARATION OF SPIROCYCLES AND AN ALLYLSILANE BASED BIFUNCTIONAL ACCEPTOR-DONOR ANNULATING REAGENT.

A simple, one pot, stereoconvergent synthesis of spirocycles has been achieved in excellent yield.Further studies on one step bifunctional annulating reagents have resulted in the development of a new allylsilane based cyclopentannulation reaction.