108264-45-5Relevant academic research and scientific papers
Synthesis of Cycloalkanones by Olefin Cyclization Initiated by Pummerer Reaction Products
Ishibashi, Hiroyuki,Harada, Suzumi,Okada, Motofumi,Ikeda, Masazumi,Ishiyama, Ko-ichi,et al.
, p. 847 - 849 (2007/10/02)
On treatment with trifluoroacetic anhydride, 1-methylsulfinyl-5-hepten-2-one undergoes cyclization via its Pummerer reaction product to give 3-ethenyl-2-(methylthio)cyclopentanone.This scope of the reaction for synthesis of cyclohexanone and cycloheptanone derivatives was explored.
