1083008-72-3Relevant academic research and scientific papers
Exploring ligand non-innocence of coordinatively-versatile diamidodipyrrinato cobalt complexes
Saund, Simran S.,Goldschmid, Samantha L.,Ng, Karina,Stewart, Veronica,Siegler, Maxime A.,Thoi, V. Sara
supporting information, p. 1825 - 1828 (2019/02/12)
The non-innocence of diamidodipyrrin is explored in a series of cobaltous complexes with novel binding motifs. By varying the coordination modes, a reversible one-electron reduction is remarkably shifted by nearly 200 mV in a single metal-ligand platform. Our study illustrates a new strategy for modifying the redox activity of porphyrin-like scaffolds.
Hydrogen-bond rigidified BODIPY dyes
Jacobsen, Jennifer A.,Stork, Jay R.,Magde, Douglas,Cohen, Seth M.
scheme or table, p. 957 - 962 (2010/04/04)
Boron difluoride adducts of diamidodipyrromethenes have been synthesized and characterized. The compounds represent a new group of the BODIPY family of fluorescent dyes. X-ray crystallography and solution 19F NMR experiments show that a persistent hydrogen bond is formed between the boron-bound fluoride groups and the peripheral amide substituents. The modular synthesis of these compounds and their robust photophysical properties suggest that they may be useful compounds for materials and biological photochemical applications.
