108306-63-4Relevant academic research and scientific papers
Halogenated 2′-chlorobithiazoles via Pd-catalyzed cross-coupling reactions
Stanetty, Peter,Schnuerch, Michael,Mihovilovic, Marko D.
, p. 3754 - 3761 (2006)
Halogenated bithiazoles allow facile further functionalization and are, therefore, suitable intermediates for the synthesis of compounds with interesting biological activity or material science properties. The applicability of three coupling methods (Negi
BISAMID-ZINKBASEN
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Page/Page column 7-8, (2010/07/04)
The present invention relates to zinc amide bases of the general formula (I) [in-line-formulae](R1R2N)2—Zn.aMgX12.bLiX2??(I)[/in-line-formulae] wherein R1 and R2 are e
(tmp)2Zn·2 MgCl2·2 LiCl: A chemoselective base for the directed zincation of sensitive arenes and heteroarenes
Wunderlich, Stefan H.,Knochel, Paul
, p. 7685 - 7688 (2008/09/18)
(Chemical Equation Presented) Positive zincing: A wide range of polyfunctional aryl and heteroaryl zinc reagents were efficiently prepared in THF by direct zincation using (tmp)2Zn·2 MgCl 2·2 LiCl (1), an exceptionally active base. Ester and cyano functions as well as aldehydes and nitro groups are tolerated. dba = dibenzylideneacetone, tmp = 2,2,6,6-tetramethylpiperidide.
Synthesis of Stannylthiazoles and Mixed Stannylsilylthiazoles and their Use for a Convenient Preparation of Mono- and Bis-halothiazoles
Dondoni, A.,Mastellari, A. R.,Medici, A.,Negrini, E.,Pedrini, P.
, p. 757 - 760 (2007/10/02)
Stannylthiazoles and stannyl-silylthiazoles have been prepared and employed as thiazolyl carbanion equivalents in reactions with halogens to give mono- and mixed bis-halothiazoles in good yields.
