108354-12-7 Usage
Definition
ChEBI: An A-type aurachin that is quinoline N-oxide which is substituted by a methyl group at position 2, a hydroxy group at position 3, and a triprenyl group at position 4.
Check Digit Verification of cas no
The CAS Registry Mumber 108354-12-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,8,3,5 and 4 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 108354-12:
(8*1)+(7*0)+(6*8)+(5*3)+(4*5)+(3*4)+(2*1)+(1*2)=107
107 % 10 = 7
So 108354-12-7 is a valid CAS Registry Number.
InChI:InChI=1/C25H33NO2/c1-18(2)10-8-11-19(3)12-9-13-20(4)16-17-23-22-14-6-7-15-24(22)26(28)21(5)25(23)27/h6-7,10,12,14-16,27H,8-9,11,13,17H2,1-5H3/b19-12+,20-16+
108354-12-7Relevant articles and documents
A semipinacol rearrangement directed by an enzymatic system featuring dual-function FAD-dependent monooxygenase
Katsuyama, Yohei,Harmrolfs, Kirsten,Pistorius, Dominik,Li, Yanyan,Müller, Rolf
, p. 9437 - 9440 (2012)
The biosynthesis of aurachins includes the intriguing migration of the prenyl group by a pinacol-type rearrangement. In vitro analysis of AuaGH revealed that these enzymes catalyze epoxidation coupled with semipinacol rearrangement (see scheme) and ketoreduction. Thus, the AuaGH system was revealed to be a novel enzymatic system for establishing semipinacol rearrangements.
