108400-97-1Relevant articles and documents
Highly selective palladium-benzothiazole carbene-catalyzed allylation of active methylene compounds under neutral conditions
Monopoli, Antonio,Cotugno, Pietro,Zambonin, Carlo G.,Ciminale, Francesco,Nacci, Angelo
, p. 994 - 999 (2015)
The Pd-benzothiazol-2-ylidene complex I was found to be a chemoselective catalyst for the Tsuji-Trost allylation of active methylene compounds carried out under neutral conditions and using carbonates as allylating agents. The proposed protocol consists in a simplified procedure adopting an in situ prepared catalyst from Pd2dba3 and 3-methylbenzothiazolium salt V as precursors. A comparison of the performance of benzothiazole carbene with phosphanes and an analogous imidazolium carbene ligand is also proposed.
Palladium(0)-catalyzed substitution of allylic substrates in a two-phase aqueous-organic medium
Safi, Mohamed,Sinou, Denis
, p. 2025 - 2028 (1991)
Palladium(0)-catalyzed substitution of allylic substrates are shown to occur in a two-phase aqueousorganic medium using the sulfonated triphenylphosphine P(C6H4-m-SO3Na)3 or (tppts) as the ligand, allowing the easy recovery and recycling of the catalyst.
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Lauer,Kilburn
, p. 2586 (1937)
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Influence du cuivre sur la substitution des enolates stables par divers halogenures allyliques
Cuvigny, Therese,Julia, Marc
, p. 121 - 138 (1987)
The allylic substitution, by a variety of allylic halides, of stable enolates derived from diethyl malonate, ethyl cyanoacetate, ethyl acetoacetate and acetylacetone has been investigated.The yields and regioselectivity of these reactions are strongly influenced by cuprous ions (and their ligands).
Monoallylation and benzylation of dicarbonyl compounds with alcohols catalysed by a cationic cobalt(iii) compound
Chandra Sau, Mohan,Mandal, Smita,Bhattacharjee, Manish
, p. 9235 - 9245 (2021/03/16)
Monoallylation and monoalkylation of diketones and β-keto esters with allylic and benzylic alcohols catalysed by [Cp*Co(CH3CN)3][SbF6]2(I) are reported. The method does not require any additive and affords regioselective products. The mechanistic investigations were done byin situ1H NMR spectroscopy as well as control experiments. It has been shown that reactions proceedviaη3-allyl complex formation or ally ether intermediate. The alkylation takes placeviaonly ether intermediate. The resulting allylated and alkylated products have been used for the synthesis of eleven new trisubstituted pyrazoles and one pyrazolone.
Palladium-Catalyzed Oxidative Cycloisomerization of 2-Cinnamyl-1,3-Dicarbonyls: Synthesis of Functionalized 2-Benzyl Furans
Nallagonda, Rajender,Reddy, Reddy Rajasekhar,Ghorai, Prasanta
supporting information, p. 14732 - 14736 (2015/10/19)
A new palladium-catalyzed intramolecular oxidative cycloisomerization of readily available starting materials, 2-cinnamyl-1,3-dicarbonyls, has been demonstrated for the creation of structurally diverse 2-benzyl furans. The cycloisomerization occurs by a regioselective 5-exo-trig pathway. The reaction shows a broad substrate scope with good to excellent yields. Furthermore, a one-pot procedure has been executed by using readily available cinnamyl alcohols and 1,3-diketones. Cinnamyl verit: Palladium-catalyzed intramolecular oxidative cycloisomerization of readily available 2-cinnamyl-1,3-dicarbonyls affords structurally diverse 2-benzyl furans. The cycloisomerization occurs by a regioselective 5-exo-trig pathway, with a broad substrate scope in good to excellent yields. Furthermore, a one-pot procedure is executed by using readily available cinnamyl alcohols and 1,3-diketones