108412-94-8Relevant articles and documents
Enantioselective synthesis of macrocyclic heterobiaryl derivatives of molecular asymmetry by molybdenum-catalyzed asymmetric ring-closing metathesis
Okayama, Yoichi,Tsuji, Satoru,Toyomori, Yuka,Mori, Atsunori,Arae, Sachie,Wu, Wei-Yi,Takahashi, Tamotsu,Ogasawara, Masamichi
, p. 4927 - 4931 (2015)
Winding vine-shaped molecular asymmetry is induced by enantioselective ring-closing metathesis with a chiral molybdenum catalyst. The reaction proceeds under mild conditions through an E-selective ring-closing metathesis leading to macrocyclic bisazoles w
Tin-free radical sequences under acidic conditions. Convergent access to azole-containing structures
Gagosz, Fabien,Zard, Samir Z.
, p. 4345 - 4348 (2007/10/03)
(equation presented) Various xanthates add efficiently to olefins bearing [1,2,4]triazole, imidazole, or benzimidazole moieties in the presence of camphorsulfonic acid via a radical chain reaction initiated by a small amount of lauroyl peroxide. The adducts may be transformed to more complex molecules by implementing a further radical cyclization.