108415-82-3Relevant academic research and scientific papers
COMPETITION BETWEEN VINYLIC SUBSTITUTION AND CONJUGATE ADDITION IN THE REACTIONS OF VINYL SELENOXIDES AND VINYL SELENONES WITH NUCLEOPHILES IN DMF
Tiecco, Marcello,Chianelli, Donatella,Testaferri, Lorenzo,Tingoli, Marco,Bartoli, Donatella
, p. 4889 - 4896 (2007/10/02)
Vinyl selenoxides and vinyl selenones present a different reactivity towards thiolate or alkoxide anions in DMF.In the case of selenoxides the addition of the nucleophiles regioselectively occurs at the α-carbon leading to the formation of the vinylic sub
